Online ISSN: 1521-3773 Print ISSN: 1433-7851
Angewandte Chemie International Edition
Volume
39, Issue
1,
2000.
© 2000 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany
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Online ISSN: 1521-3773 Print ISSN: 1433-7851 © 2000 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany |
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Life at the End of the Chromosome: Telomeres and Telomerase Thomas R. Cech Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<34::AID-ANIE34>3.0.CO;2-N |
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The Art and Science of Total Synthesis at the Dawn of the Twenty-First Century K. C. Nicolaou, Dionisios Vourloumis, Nicolas Winssinger, Phil S. Baran Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<44::AID-ANIE44>3.0.CO;2-L |
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Ferrocene: Ironclad History or Rashomon Tale? Pierre Laszlo, Roald Hoffmann Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<123::AID-ANIE123>3.0.CO;2-Z |
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Thermochemical Data of Organic Ions Obtained from Investigations in the More or Less Diluted Gas Phase Dietmar Kuck Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<125::AID-ANIE125>3.0.CO;2-R |
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Simple Carbonyls of Ruthenium: New Avenues from the Hieber Base Reaction Anthony F. Hill Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<130::AID-ANIE130>3.0.CO;2-6 |
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Resorcarene-Based Nanoarchitectures: Metal-Directed Assembly of a Molecular Loop and Tetrahedron O. Danny Fox, Michael G. B. Drew, Paul. D. Beer Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<135::AID-ANIE135>3.0.CO;2-N |
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Carbohydrates Exhibit a Distinct Preferential Solvation Pattern in Binary Aqueous Solvent Mixtures Aleksey Vishnyakov, Göran Widmalm, Aatto Laaksonen Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<140::AID-ANIE140>3.0.CO;2-2 |
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Thermoregulated Optical Properties of Peptidic Pseudorotaxanes Jean-Christophe Meillon, Normand Voyer, Éric Biron, François Sanschagrin, J. Fraser Stoddart Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<143::AID-ANIE143>3.0.CO;2-R |
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Application of Combinatorial Procedures in the Search for Serine-Protease-Like Activity with Focus on the Acyl Transfer Step Hilde De Muynck, Annemieke Madder, Nadia Farcy, Pierre J. De Clercq, M. Nieves Pérez-Payán, Liselotte M. Öhberg, Anthony P. Davis Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<145::AID-ANIE145>3.0.CO;2-J |
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A Self-Complexing [2]Catenane Beatriz Cabezon, Jianguo Cao, Françisco M. Raymo, J. Fraser Stoddart, Andrew J. P. White, David J. Williams Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<148::AID-ANIE148>3.0.CO;2-7 |
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X-Ray, Molecular Diffusion, and NOESY NMR Studies of Chiral, Tetranuclear CuI Catalysts Based on Monodentate Thiol Analogues of TADDOL Arkadius Pichota, Paul S. Pregosin, Massimiliano Valentini, Michael Wörle, Dieter Seebach Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<153::AID-ANIE153>3.0.CO;2-N |
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Acetyl Substitution of the O-Specific Caryan from the Lipopolysaccharide of Pseudomonas (Burkholderia) caryophylli Leads to a Block Pattern Antonio Molinaro, Cristina De Castro, Bent O. Petersen, Jens ? Duus, Michelangelo Parrilli, Otto Holst Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<156::AID-ANIE156>3.0.CO;2-B |
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Anchoring of Functional Dye Molecules in MCM-41 by Microwave-Assisted Hydrothermal Cocondensation Matthias Ganschow, Michael Wark, Dieter Wöhrle, Günter Schulz-Ekloff Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<160::AID-ANIE160>3.0.CO;2-V |
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Immobilization of TADDOL with a High Degree of Loading on Porous Silica Gel and First Applications in Enantioselective Catalysis Alexander Heckel, Dieter Seebach Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<163::AID-ANIE163>3.0.CO;2-J |
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Phosphane-Free Palladium-Catalyzed Coupling Reactions: The Decisive Role of Pd Nanoparticles Manfred T. Reetz, Elke Westermann Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<165::AID-ANIE165>3.0.CO;2-B |
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The Tetrakis(carbonyl)dioxoosmium(VI) Cation: trans-[OsO2(CO)4]2+ Eduard Bernhardt, Helge Willner, Volker Jonas, Walter Thiel, Friedhelm Aubke Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<168::AID-ANIE168>3.0.CO;2-# |
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A Facile Route to Group 13 Difluorodiorganometalates: [nBu4N][R2MF2] (M=Al, Ga, In) Herbert W. Roesky, Andreas Stasch, Hagen Hatop, Carsten Rennekamp, David H. Hamilton, Mathias Noltemeyer, Hans-Georg Schmidt Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<171::AID-ANIE171>3.0.CO;2-N |
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Palladium-Catalyzed Intermolecular Controlled Insertion of Benzyne-Benzyne-Alkene and Benzyne-Alkyne-Alkene - Synthesis of Phenanthrene and Naphthalene Derivatives Eiji Yoshikawa, Yoshinori Yamamoto Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<173::AID-ANIE173>3.0.CO;2-F |
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The Dendritic Effect in Homogeneous Catalysis with Carbosilane-Supported Arylnickel(II) Catalysts: Observation of Active-Site Proximity Effects in Atom-Transfer Radical Addition Arjan W. Kleij, Robert A. Gossage, Johann T. B. H. Jastrzebski, Jaap Boersma, Gerard van Koten Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<176::AID-ANIE176>3.0.CO;2-3 |
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Aluminum Bis(trifluoromethylsulfonyl)amides: New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions Andreas Marx, Hisashi Yamamoto Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<178::AID-ANIE178>3.0.CO;2-W |
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Ordered Two-Dimensional Monolayers of Au55 Clusters Günter Schmid, Monika Bäumle, Norbert Beyer Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<181::AID-ANIE181>3.0.CO;2-J |
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Controlling Electronic Communication in Ethynylated-Polypyridine Metal Complexes Abdelkhrim El-ghayoury, Anthony Harriman, Abderrahim Khatyr, Raymond Ziessel Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<185::AID-ANIE185>3.0.CO;2-3 |
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[Ti(CO)4(3-BH4)]- and [Ti(CO)4(5-C4H4N)]-: The First Zerovalent Metal Complexes Containing 3-Borohydride and Pyrrolyl Ligands Paul J. Fischer, Victor G. Young, Jr., John E. Ellis Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<189::AID-ANIE189>3.0.CO;2-O |
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A Metamagnetic Two-Dimensional Molecular Material with Nickel(II) and Azide Montserrat Monfort, Immaculada Resino, Joan Ribas, Helen Stoeckli-Evans Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<191::AID-ANIE191>3.0.CO;2-F |
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Bis-Capsules: Cooperative Reversible Encapsulation of Two Molecules in Adjacent Separate Chambers Naveen Chopra, Christoph Naumann, John C. Sherman Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<194::AID-ANIE194>3.0.CO;2-3 |
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A Two-Step Spin Crossover in [(TPA)FeIII(cat)]BPh4 A. Jalila Simaan, Marie-Laure Boillot, Eric Rivière, Alain Boussac, Jean-Jacques Girerd Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<196::AID-ANIE196>3.0.CO;2-W |
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O-HPtII: Hydrogen Bond with a Strong Dispersion Component Ji?Kozelka, Jacqueline Bergès, Roger Attias, Jann Fraitag Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<198::AID-ANIE198>3.0.CO;2-O |
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Investigations of Thin Films with Amphiphilic Dendrimers Bearing Peripheral Fullerene Subunits Delphine Felder, Jean-Louis Gallani, Daniel Guillon, Benoît Heinrich, Jean-François Nicoud, Jean-François Nierengarten Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<201::AID-ANIE201>3.0.CO;2-A |
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Acetamidoglycosylation with Glycal Donors: A One-Pot Glycosidic Coupling with Direct Installation of the Natural C(2)-N-Acetylamino Functionality Valeria Di Bussolo, Jing Liu, Larry G. Huffman, Jr., David Y. Gin Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<204::AID-ANIE204>3.0.CO;2-Z |
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[{Pt(CO)3}2]2+: The First Homoleptic, Dinuclear, Cationic Platinum(I) Carbonyl Complex Formed in Concentrated Sulfuric Acid Qiang Xu, Yoshie Souma, Brian T. Heaton, Chacko Jacob, Kan Kanamori Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<208::AID-ANIE208>3.0.CO;2-J |
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Enantioselective Total Synthesis of Epothilone A Using Multifunctional Asymmetric Catalyses Daisuke Sawada, Masakatsu Shibasaki Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<209::AID-ANIE209>3.0.CO;2-F |
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Enantioselective Construction of Vicinal Stereogenic Quaternary Centers by Dialkylation: Practical Total Syntheses of (+)- and meso-Chimonanthine Larry E. Overman, Jay F. Larrow, Brian A. Stearns, Jennifer M. Vance Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<213::AID-ANIE213>3.0.CO;2-Z |
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How Strong Is the Coordination Bond between a Histidine Tag and Ni - Nitrilotriacetate? An Experiment of Mechanochemistry on Single Molecules Matteo Conti, Giuseppe Falini, Bruno Samor?br> Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<215::AID-ANIE215>3.0.CO;2-R |
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Denticity Changes of Hydrotris(pyrazolyl)borate Ligands in RhI and RhIII Compounds: From 3- to Ionic 0-Tp Margarita Paneque, Sabine Sirol, Marianela Trujillo, Enrique Gutiérrez-Puebla, M. Angeles Monge, Ernesto Carmona Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<218::AID-ANIE218>3.0.CO;2-F |
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Synthesis and Structures of 1,3,5,7-Tetraazaheptatrienylsodium and -thallium(I) W. Marco Boesveld, Peter B. Hitchcock, Michael F. Lappert, Heinrich Nöth Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<222::AID-ANIE222>3.0.CO;2-Z |
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Genetic Engineering of Streptomyces coelicolor A3(2) for the Enantioselective Reduction of Unnatural -Keto-Ester Substrates Christopher E. Anson, Maureen J. Bibb, Kevin I. Booker-Milburn, Cole Clissold, Patrick J. Haley, David A. Hopwood, Koji Ichinose, W. Peter Revill, G. Richard Stephenson, Chandres M. Surti Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<224::AID-ANIE224>3.0.CO;2-R |
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Twist Sense Bias Induced by Chiral Side Chains in Helically Folded Oligomers Ryan B. Prince, Luc Brunsveld, E. W. Meijer, Jeffrey S. Moore Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<228::AID-ANIE228>3.0.CO;2-B |
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Mixed-Valent Heptairon Complex with a Ground-State Spin Value of S=12/2 Constructed from a Triiron Cluster Ligand Takashi Kajiwara, Tasuku Ito Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<230::AID-ANIE230>3.0.CO;2-2 |
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Encoded Helical Self-Organization and Self-Assembly into Helical Fibers of an Oligoheterocyclic Pyridine - Pyridazine Molecular Strand Louis A. Cuccia, Jean-Marie Lehn, Jean-Claude Homo, Marc Schmutz Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<233::AID-ANIE233>3.0.CO;2-R |
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A New Enantioselective Approach to Total Synthesis of the Securinega Alkaloids: Application to (-)-Norsecurinine and Phyllanthine Gyoonhee Han, Matthew G. LaPorte, James J. Folmer, Kim M. Werner, Steven M. Weinreb Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<237::AID-ANIE237>3.0.CO;2-B |
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Formal Three-Electron Reduction by an f-Element Complex: Formation of [{(C5Me5)(C8H8)U}2(C8H8)] from Cyclooctatetraene and [(C5Me5)3U] William J. Evans, Gregory W. Nyce, Joseph W. Ziller Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<240::AID-ANIE240>3.0.CO;2-Z |
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Application of Reductive Samariation to the Synthesis of Small Unnatural Peptides Marina Ricci, Leire Madariaga, Troels Skrydstrup Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<242::AID-ANIE242>3.0.CO;2-R |
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Antiferromagnetic Coupling in a Gadolinium(III) Semiquinonato Complex Andrea Caneschi, Andrea Dei, Dante Gatteschi, Lorenzo Sorace, Kira Vostrikova Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<246::AID-ANIE246>3.0.CO;2-B |
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Improved Electrochemistry in Low-Polarity Media Using Tetrakis(pentafluorophenyl)borate Salts as Supporting Electrolytes Robert J. LeSuer, William E. Geiger Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<248::AID-ANIE248>3.0.CO;2-3 |
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Combinatorial Synthesis of Four-Helix Bundle Hemoproteins for Tuning of Cofactor Properties Harald K. Rau, Niels DeJonge, Wolfgang Haehnel Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<250::AID-ANIE250>3.0.CO;2-V |
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Complete Carbonylation of fac-[Tc(H2O)3(CO)3]+ under CO Pressure in Aqueous Media: A Single Sample Story! Nicolas Aebischer, Roger Schibli, Roger Alberto, Andr?E. Merbach Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<254::AID-ANIE254>3.0.CO;2-F |
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Femtosecond Dynamics of Dioxygen - Picket-Fence Cobalt Porphyrins: Ultrafast Release of O2 and the Nature of Dative Bonding Beat Steiger, J. Spencer Baskin, Fred C. Anson, Ahmed H. Zewail Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<257::AID-ANIE257>3.0.CO;2-3 |
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Femtosecond Dynamics of Norrish Type-II Reactions: Nonconcerted Hydrogen-Transfer and Diradical Intermediacy Steven De Feyter, Eric W.-G. Diau, Ahmed H. Zewail Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<260::AID-ANIE260>3.0.CO;2-R |
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An EPR Investigation of the Kinetics of Inclusion of a Persistent Radical in Water-Soluble Calix[4]arenes Paola Franchi, Marco Lucarini, Gian Franco Pedulli, Domenico Sciotto Published Online: 12 Jan 2000 DOI10.1002/(SICI)1521-3773(20000103)39:1<263::AID-ANIE263>3.0.CO;2-F |